Mains electricity is the phrase used to refer to the general-purpose 230 V AC electricity supply, as opposed to the specialist higher voltage industrial electricity supplies. You can regard it as the electricity that is supplied to normal wall sockets, lighting circuits etc. in homes and places of work like offices and shops. In GCSE Physics, mains electricity is focused on electricity in the home. Mains electricity is useful but, if used incorrectly, it can be deadly, so understanding this form of energy and how to use it safely is a very important life skill.
Any form of electricity is a source of energy which can be transferred into other forms of useful energy. There is usually at least one form of waste energy during any energy transfer. With home electrical appliances, it's a good bet that this waste energy will be heat (unless it is an electric heater of course!). This means that no appliance will ever be one hundred percent efficient, but some come quite close.